In situ polymerization of flame retardant modification polyamide 6,6 with 2-carboxy ethyl (phenyl) phosphinic acid

A novel halogen-free flame retardant copolyamide 6,6 (FR-PA66) was prepared successfully by in situ polymerizing with adipic acid hexamethylene salt and 2-carboxy ethyl (phenyl) phosphinic acid (CEPPA). The elemental composition and chemical structure of FR-PA66 were characterized by energy dispersive X-ray spectroscopy, Fourier transform infrared spectrometer and ¹³C Nuclear magnetic resonance spectrometer. The flame retardancy, thermal stability, and morphology of char residues were also investigated by the limiting oxygen index (LOI), UL 94 test, thermogravimetric analysis, and scanning electron microscopy. The results showed that FR-PA66 samples had much better flame retardancy and char formation ability than pure PA66 after the flame retardant modification. The LOI values were increased from 24.0 to 28.0% by adding 6 wt % of CEPPA and all FR-PA66 samples were rated as V-0 rating in UL-94 test. Furthermore, the thermal stability analysis indicated that in situ polymerization with CEPPA effectively decreased the initial decomposition temperature and increased the amount of char residue. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 137, 48687.     

塑料薄膜材料在微藻培养环境中的稳定性和生物附着行为

考察了6种薄膜材料在次氯酸钠(NaClO)溶液、HCl溶液(pH=2)和NaOH溶液(pH=12)中的稳定性及其在普通小球藻培养体系中的生物附着行为。结果表明，聚氯乙烯(PVC)在3种溶液中浸泡后420 nm处的透光率下降约50%，聚氨酯(PU)在NaClO溶液中、乙烯?醋酸乙烯酯(EVA)在NaOH溶液中浸泡后420 nm处的透光率下降10%?15%，聚乙烯(PE)、聚丙烯(PP)和聚对苯二甲酸乙二醇酯(PET)在3种溶液中浸泡后的透光率没有明显变化；6种薄膜材料在普通小球藻培养体系中均有微藻明显附着，浸泡7 d后透光率明显下降，其中PVC表面附着最严重，浸泡7 d后透光率接近0，附着物量随浸泡时间延长而增加，浸泡45 d后达3069 ?g/cm2；其它5种薄膜表面附着物量先增加后降低，PU和EVA在第15 d时、PE, PP和PET在第30 d时附着物量最大，分别为292, 375, 292, 194和236 ?g/cm2。     

7050铝合金单峰时效热处理工艺及性能研究

利用材料相图及性能模拟软件JMatPro对7050铝合金进行模拟计算，得到7050铝合金的TTT和CCT曲线。合金的TTT曲线整体呈“C”形，GP区、亚稳相和稳定相鼻尖温度分别为140、330、380 ℃，对应的孕育时间为0.002、0.007、0.200 h，η′相无析出的临界冷却速率为2 ℃/s。采用力学性能和电镜组织观察的方法，研究7050铝合金单峰时效热处理工艺。结果表明:当温度达到485 ℃时，在DSC曲线上出现吸热峰；在120 ℃下进行时效处理，随着时效时间的延长，合金的强度硬度持续增加，合金断后伸长率先增加后减小，时效70 h未见过时效特征，当时效8 h时，合金强度和韧性有较好配合，抗拉强度为593 MPa，屈服强度为516 MPa，断后伸长率为12.6%，试样拉伸断口均呈现穿晶韧窝型断裂与沿晶断裂的混合式断口形貌。     

金刚石涂层微铣刀的铣削加工试验

为了掌握金刚石涂层对其铣削性能的影响，针对直径为50 μm级的硬质合金微铣刀，进行了金刚石涂层与未涂层硬质合金微铣刀具微槽铣削试验。通过使用线电极电火花磨削技术制备出直径为50 μm级的D形微铣刀,采用金刚石涂层和未涂层刀具在纯铜工件上开展微槽铣削工艺试验；使用白光干涉仪、超景深显微镜等仪器来观测微槽表面形貌、粗糙度等随铣削距离变化的规律，分析金刚石涂层对硬质合金微铣刀铣削加工质量的影响。结果表明：采用金刚石涂层刀具加工的微槽具有较少的毛刺，表面粗糙度值约为未涂层刀具铣削的粗糙度值的1/2，并且能够在一定距离内保持稳定的槽宽、粗糙度值和侧面形貌。     

大红山铁矿盲小矿体地质勘探技术思路

目前大红山铁矿400万t/a一期采矿工程已接近尾声，现已转入二期工程。随着矿山主矿体的开采，面临着矿石资源量较少、富余人员增多等问题。因此边部盲小矿体开采显得意义更加重大。矿体边部受控矿地质构造的影响，加之前期探矿工程有限，矿体边部盲小矿体未能得到有效控制。通过对大红山井下主矿体边部尤其是南部靠近侵入体边部隐伏盲小矿体特征的分析，实施了“探边扫盲”生产地质勘探工作，为矿山开采提供了资源补充。     

苏通GIL运输专用机具动力电池类型探讨

GIL运输专用机具是为安全、可靠、高效地完成苏通GIL综合管廊工程GIL单元的运输任务而研制的专用机具,其中动力电池系统设计是整机设计的重点之一。通过对各种常见动力电池优缺点的分析,并结合苏通GIL运输专用机具对动力电池的需求分析,确定了动力电池系统的技术路线,为苏通GIL运输专用机具的研制提供了坚实的基础。     

Structure,electrical and dielectric properties of Ca substituted BaTiO3 ceramics

BaTi_1-xCa_xO_3-x [BTC100x] ceramics were synthesized via solid-state reaction method. Effect of Ca substitution on the structure, electrical and dielectric properties of BTC100x ceramics was systematically investigated. Calcined BTC100x powders were in tetragonal phase when x?≤?0.01, whereas transformed to cubic at x?>?0.01. Additionally, the diffraction peak (200) shifted to lower angles with increasing x, indicating increased unit cell volume. Meanwhile, Ba_0.97Ca_0.03TiO₃ [BC3T] ceramic was prepared and studied, to compare with BaTi_0.97Ca_0.03O_2.97 (BTC3). It was found that pure BaTiO₃ [BT] and BC3T ceramics had the similar structural and dielectric properties, whereas BTC3 ceramic showed much difference，XRD patterns, Raman spectrum, impedance spectra and dielectric-temperature spectra provided strong evidence of Ca²⁺ substitution at Ti site in BT lattice. Finally, BTC100x ceramics were produced and dielectric properties were investigated. With increasing x, the Curie temperature decreased from 128?°C (BT) to 42?°C (BTC5).     

Electrolytic synthesis of TiC/SiC nanocomposites from high titanium slag in molten salt

The molten salt electrolytic method for the preparation of titanium carbide and silicon carbide composites has been subjected to a systematic investigation by experimental analyses and thermodynamic calculations. It has been confirmed that the electrolysis of high titanium slag in the presence of mixed graphite powders generates intermediates CaTiO₃, Ti₂O₃, TiO, Fe₃Si and objective carbonous products TiC/SiC. It has been furthermore found that the deoxidization process depends critically on a number of process parameters, namely, electrolyte composition, graphitic regime, reaction temperature, cell voltage and reaction time. After careful optimization of these parameters, TiC/SiC nanocomposites with particle sizes of 10–174 nm has been produced by electrolysis of high titanium slag and graphite mixtures in molar ratio of 1:2 referred to Ti:C under 3.2 V at 900 °C for 6 h in 1 mol%CaO-CaCl₂-NaCl molten salt and with particle sizes of 12 nm~207 nm in 1 mol%CaO-CaCl₂ electrolyte.     

Three‐dimensional color prediction modeling of single‐ and double‐layered woven fabrics

In this research, the three‐dimensional structural and colorimetric modeling of three‐dimensional woven fabrics was conducted for accurate color predictions. One‐hundred forty single‐ and double‐layered woven samples in a wide range of colors were produced. With the consideration of their three‐dimensional structural parameters, three‐dimensional color prediction models, K/S‐, R‐, and L*a*b*‐based models, were developed through the optimization of previous two‐dimensional models which have been reported to be the three most accurate models for single‐layered woven structures. The accuracy of the new three‐dimensional models was evaluated by calculating the color differences ΔL*, ΔC*, Δh°, and ΔE_CMC(2:1) between the measured and the predicted colors of the samples, and then the error values were compared to those of the two‐dimensional models. As a result, there has been an overall improvement in color predictions of all models with a decrease in ΔE_CMC(2:1) from 10.30 to 5.25 units on average after the three‐dimensional modeling.